引言.................................................................................................(1)

第一篇海洋防污

第一章防污概述...................................................................................(3)

一、防污的目的意义...............................................................................................(3)

二、污损生物........................................................................................................(4)

三、国产沥青防污漆简介........................................................................................(5)

四、日本所使用的防污剂.........................................................................................(5)

五、防污涂料的动向...............................................................................................(7)

第二章氧化亚铜和铜类防污剂............................................................................(9)

一、氧化亚铜的防污作用........................................................................................(9)

二、氧化亚铜的性能和制法....................................................................................(9)

1.性能.......................................................................................................................(9)

2.国内制法.................................................................................................................(9)

3.利用废液制造氧化亚铜.................................................................................................(10)

三、铜类防污涂料配方实例......................................................................................(11)

1.氧化亚铜松香鱼油涂料.................................................................................................(11)

2.氧化亚铜、松香和蜡.....................................................................................................(11)

3.热溶性氧化亚铜酚醛涂料...............................................................................................(12)

4.不饱和聚酯树脂型氧化亚铜防污涂料...........................................................................(13)

5.氧化亚铜弹性防污涂料..................................................................................................(13)

6.二氯苯基二氯乙烷-氧化亚铜防污涂料...............................................................................(14)

7.低碳烷基硫醇的铜盐防污剂............................................................................................(14)

8.氢氧化铜防污涂料........................................................................................................(14)

9.乙烯类防污涂料...................................................................................................(14)

10.氧化亚铜氯化橡胶防污涂料.............................................................................................(14)

11.防污涂料中填料的选择.............................................................................................(15)

12.含磷和铜的防污涂料.....................................................................................................(15)

13.低摩擦防污涂料...........................................................................................................(15)

14.包有铜化物的二氧化硅防污颜料.......................................................................................(15)

15.硼酸盐玻璃态防污颜料....................................................................................................(16)

16.铜和咪唑啉的络合物.......................................................................................................(16)

17.杀菌剂的作用..............................................................................................................(17)

四、氧化亚铜防污涂料测试方法举例..........................................................................(17)

五、国产氧化亚铜防污漆的防沉淀问题.......................................................................(18)

第三章有机金属化合物防污剂.................................................................(19)

一、有机锡防污剂...................................................................................................(19)

1. 概述...........................................................................................................................(19)

2.有机锡防污剂的制备和性能...............................................................................................(20)

3.有机锡防污涂料举例.......................................................................................................(27)

二、有机铅防污剂.................................................................................................(33)

1.有机铅防污剂的制备........................................................................................................(33)

2.有机铅弹性防污涂料的性能和特点...................................................................................(34)

3.防污涂料的毒性释放试验及分析结果..................................................................................(34)

三、其他有机金属防污剂.........................................................................................(35)

1.有机锑防污剂..................................................................................................................(35)

2.有机铋化合物................................................................................................................(36)

3.对苯二甲酸的重金属盐....................................................................................................(37)

4.锰盐...........................................................................................................................(37)

5.有机汞化合物..................................................................................................................(37)

第四章高分子防污剂....................................................................................(39)

一、引言——防污剂的控制释放理论..........................................................................(39)

二、丙烯酸型有机锡共聚物......................................................................................(41)

1.有机锡聚合物和二元共聚物........................................................................................(41)

2.有机锡丙烯酸三元共聚物.........................................................................................(42)

3.憎水性有机延缓剂.........................................................................................................(43)

4.有机锡聚合物防污涂料的配方原理和实例............................................................................(44)

5.丙烯酸有机锡共聚物的防污作用和自抛光作用.....................................................................(45)

6.丙烯酸型有机锡共聚物配方举例........................................................................................(46)

7.提高有机锡共聚物防污涂料的稳定性...............................................................................(47)

8.其他新型长效防污涂料................................................................................................(47)

二、有机锡醇酸树脂..............................................................................................(47)

四、有机锡顺丁烯二酸酐缩聚物或共聚物.....................................................................(49)

五、含锡有机硅防污涂料..........................................................................................(49) 2100433B